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Preheat oven to 350 degrees.
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If you have a bowl that fits at least 12 cups of ingredients, go ahead and make this batch as the ingredients are listed above for a 4-layered cake. However, if you do not, halve the ingredients and make two batches. (Half of ⅓ c. = 3 T.+1 t. )
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Combine butter and sugar in a large bowl of a high speed mixer. Mix for 2 minutes on medium speed.
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In a separate bowl, combine white rice flour, tapioca starch, xanthan gum, baking powder, and salt. Add in about 1 c. of dry ingredients to the butter/sugar bowl. Mix for 30 seconds.
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Add eggs, one at a time, mixing well after each addition. Add in vanilla and almond extract.
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Add remaining dry ingredients and buttermilk alternatively, starting and ending with dry ingredients. Beat for an additional minute to make batter light and fluffy.
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Fill four well-greased 9-inch round cake pans with even amounts of cake batter. Bake for 25-30 minutes, or until a toothpick inserted in the center comes out clean.
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Let cool for 5-10 minutes before flipping out.